Search results for "Materials Science | Hot Paper"
showing 10 items of 1457 documents
Towards Atomically Precise Supported Catalysts from Monolayer‐Protected Clusters: The Critical Role of the Support
2020
Abstract Controlling the size and uniformity of metal clusters with atomic precision is essential for fine‐tuning their catalytic properties, however for clusters deposited on supports, such control is challenging. Here, by combining X‐ray absorption spectroscopy and density functional theory calculations, it is shown that supports play a crucial role in the evolution of monolayer‐protected clusters into catalysts. Based on the acidic nature of the support, cluster‐support interactions lead either to fragmentation of the cluster into isolated Au–ligand species or ligand‐free metallic Au0 clusters. On Lewis acidic supports that bind metals strongly, the latter transformation occurs while pre…
A comparative study of methanol carbonation on unsupported SnO2 and ZrO2
2009
International audience; The aim of this work was to explore the catalytic properties of SnO2 in the coupling of methanol with carbon dioxide to afford dimethyl carbonate. SnO2 nanopowders were produced by hydrolysis of tin tetra-tert-butoxide dissolved in n-butanol. The samples were much more active than a commercial one due to their higher surface areas. In addition, they exhibited excellent recyclability. However, comparison with ZrO2, prepared and tested under the same experimental conditions, showed that zirconia-based catalysts were more selective and are, among the heterogeneous catalysts already reported, still the more selective. SnO2 also catalyzed the formation of dimethyl ether l…
Radiometric calibration of SeaWIFS in the near infrared
2005
The radiometric calibration of the Sea-Viewing Wide-Field-of-View Sensor (SeaWiFS) in the near infrared (band 8, centered on 865 nm) is evaluated by use of ground-based radiometer measurements of solar extinction and sky radiance in the Sun's principal plane at two sites, one located 13 km off Venice, Italy, and the other on the west coast of Lanai Island, Hawaii. The aerosol optical thickness determined from solar extinction is used in an iterative scheme to retrieve the pseudo aerosol phase function, i.e., the product of single-scattering albedo and phase function, in which sky radiance is corrected for multiple scattering effects. No assumption about the aerosol model is required. The ae…
A solar assisted seasonal borehole thermal energy system for a non-residential building in the Mediterranean area
2019
Abstract Solar heating and cooling systems are reliable and feasible solutions among renewable energy technologies. Indeed, solar thermal devices help reduce primary energy consumption and can reduce electricity demand, thus representing one of the best options for satisfying heating and/or cooling energy supply. The Borehole Thermal Energy Storage (BTES) represents one of the best promising option among the various storage technologies, because the size of the storage can be easily extended by drilling additional boreholes and simply connecting the pipes to the existing boreholes; the overall energy efficiency of this system is about 40–60%. In this paper, the authors present an applicatio…
Optimization of Vehicle-to-Vehicle Frontal Crash Model Based on Measured Data Using Genetic Algorithm
2017
In this paper, a mathematical model for vehicle-to-vehicle frontal crash is developed. The experimental data are taken from the National Highway Traffic Safety Administration. To model the crash scenario, the two vehicles are represented by two masses moving in opposite directions. The front structures of the vehicles are modeled by Kelvin elements, consisting of springs and dampers in parallel, and estimated as piecewise linear functions of displacements and velocities, respectively. To estimate and optimize the model parameters, a genetic algorithm approach is proposed. Finally, it is observed that the developed model can accurately reproduce the real kinematic results from the crash test…
The application of the random balance method in laser machining of metals
2008
International audience; Features peculiar to laser technology offer some advantages over more traditional processes, but, like all processes, it has its limitations. This article studies the limitations of laser machining of metals, and quantifies, through an experimental design method, the influence of operating parameters on productivity and on the quality of the machined surface. Three study materials were used: an aluminium alloy, stainless steel and a titanium alloy. An initial reading of the results indicates that productivity depends mainly on the frequency of the laser pulse and that the aluminium alloy behaves differently from the other two. The quality of the machined surface, jud…
Residual stress measurement in innovative friction stir welding processes
2017
In recent years, important innovations have been introduced in Friction Stir Welding (FSW) technology such as, for example, the Laser assisted Friction Stir Welding (LFSW) and in-process Cooled Friction Stir Welding (CFSW). Residual stresses have a fundamental role in welded structures because they affect the way to design the structures, fatigue life, corrosion resistance and many other material properties. Consequently, it is important to investigate the residual stress distribution in FSW where, though the heat input is lower compared to traditional welding techniques, the constraints applied to the parts to weld are more severe. The aim of the present work is to verify the capabilities …
AZ31 magnesium alloy recycling through friction stir extrusion process
2015
Friction Stir Extrusion is a novel technique for direct recycling of metal scrap. In the process, a dedicated tool produces both the heat and the pressure to compact and extrude the original raw material, i.e., machining chip, as a consolidated component. A proper fixture was used to carry out an experimental campaign on Friction Stir Extrusion of AZ31 magnesium alloy. Variable tool rotation and extrusion ratio were considered. Appearance of defects and fractures was related to either too high or too low power input. The extruded rods were investigated both from the metallurgical and mechanical points of view. Tensile strength up to 80 % of the parent material was found for the best combina…
Optimisation of refractory coatings realised with cored wire addition using a high-power diode laser
2005
Laser; Cladding; Refractory alloys; Factorial experiments; International audience; The objective or our research was to obtain refractory alloys using the high-power diode laser (HPDL) coating technique. After optimisation using factorial experiments, two different cladding regimes were clearly distinguished. It was also shown that a very narrow transition zone exists between the two regimes, and, inside this zone, clad layers having a satisfactory compromise between the response functions (surface aspect and cavity presence) were obtained. The main objective of our study, namely, the control of the operating parameters (geometrical and kinematical) to realise adequate coatings, without cav…
On the complete interface development of Al/Cu magnetic pulse welding via experimental characterizations and multiphysics numerical simulations
2021
Abstract A complex Al/Cu magnetic pulse welding interface is systematically investigated using experimental characterizations and numerical simulations. A Coupled electromagnetic-mechanical simulation is proposed to compute the impact velocity and impact angle along the entire interface. This model allows to further understand the formation mechanism of various interface characteristics during MPW. The results revealed that the impact velocity gradually decreases in conjunction with the gradual increase of the impact angle. These simulations elucidate the experimentally observed successive interface morphologies, i.e., the unwelded zone, vortex zone, intermediate (IM) layers and wavy interf…